Dichlorido{μ-6,6′-dimethoxy-2,2′-[o-phenylenebis(nitrilomethylidyne)]diphenolato}(dimethyl sulfoxide)lead(II)zinc(II) N,N-dimethylformamide solvate
نویسندگان
چکیده
In the heterodinuclear complex of the title compound, [PbZn(C(22)H(18)N(2)O(4))Cl(2)(C(2)H(6)OS)]·C(3)H(7)NO, the Zn(II) atom is coordinated in a distorted square-pyramidal geometry by two N atoms and two O atoms from the diphenolate ligand, and one Cl atom which occupies the apical position. The Pb(II) atom is coordinated in a distorted octa-hedral geometry by the four O atoms of the diphenolate ligand, one O atom from the dimethyl sulfoxide mol-ecule and one Cl atom. The dimethyl sulfoxide mol-ecule is disordered over two positions, with site occupancies of 0.576 (2) and 0.424 (2).
منابع مشابه
(Dimethylformamide-κO){4,4′,6,6′-tetrabromo-2,2′-[o-phenylenebis(nitrilomethylidyne)]diphenolato-κ4 O,N,N′,O′}copper(II) dimethylformamide solvate
In the title compound, [Cu(C(20)H(10)Br(4)N(2)O(2))(C(3)H(7)NO)]·C(3)H(7)NO, the Cu(II) ion is coordinated by two N atoms and two O atoms from a tetra-dentate Schiff base ligand and the O atom of one dimethyl-formamide ligand in an almost square-pyramidal geometry. The uncoordinated dimethyl-formamide solvent mol-ecule is disordered over two sets of positions with occupancies of 0.741 (4) and 0...
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